| Methane (CH₄) | Volume fraction, measured on a clearly stated wet or dry basis | Often approximately 50–70% by volume; actual values depend on feedstock and digester operation | Track changes during feedstock transitions, startup, and process upsets | Sets the starting methane concentration and helps estimate product-gas recovery and upgrading duty |
| Carbon dioxide (CO₂) | Volume fraction and the required CO₂ level in the product gas | Often approximately 30–50% by volume in raw biogas | Can shift as the feedstock mix, loading rate, or digester conditions change | Higher CO₂ removal requirements may affect equipment size, energy use, and methane-loss control |
| Hydrogen sulfide (H₂S) | Concentration in ppm by volume; also note short-duration peaks | May range from tens to several thousand ppm; some feed gases can exceed 10,000 ppm | Often varies with sulfur in the feedstock, operating conditions, and dosing of sulfur-control additives | Determine whether bulk desulfurization, polishing, or both are needed to protect downstream equipment and meet product specifications |
| Water vapor and dew point | Moisture content, gas temperature, pressure, and pressure dew point | Raw biogas leaving a digester is commonly saturated with water vapor at its operating temperature | Condensation changes with temperature, pressure, piping layout, and seasonal weather | Include cooling and condensate management as needed; confirm that gas is sufficiently dry for the selected process and end use |
| Oxygen and nitrogen | O₂ and N₂ concentrations, including air-ingress indicators | Usually low in well-sealed anaerobic systems, but measurable amounts can occur; levels are site-specific | Check for changes linked to leaks, air injection, or operating practices | These gases may be difficult to remove selectively and can affect product-gas quality, safety, and process selection |
| Siloxanes and volatile contaminants | Siloxanes, volatile organic compounds, and relevant trace contaminants; report the sampling method and units | Concentrations vary widely by source; landfill gas and some wastewater-derived gas may require particular attention to siloxanes | Use representative sampling because concentrations may vary with waste composition and time | Specify contaminant-specific pretreatment or polishing when required by engines, turbines, catalysts, or the product-gas specification |
| Flow rate | Minimum, normal, peak, and maximum flow in Nm³/h or another defined standard volume basis | For an illustrative site, a measured range might be 100–250 Nm³/h; this is an example, not a universal plant-size category | Record hourly and seasonal profiles, not only an average value | Size equipment for the expected operating envelope and confirm turndown capability, redundancy, and any buffer-storage needs |
| Flow and composition variability | Time-series data for flow, CH₄, CO₂, H₂S, moisture, and other relevant contaminants | Assess normal fluctuations as well as startup, shutdown, maintenance, and upset conditions | Identify peak-to-average ratios, duration of excursions, and how often they occur | Consider flexible controls, staged treatment, adequate pretreatment capacity, and alarms or bypass arrangements where appropriate |
| Product-gas specification and end use | Required methane content, contaminant limits, pressure, and delivery conditions | Requirements differ for boilers, engines, vehicle fuel, and pipeline injection; confirm the applicable local specification | Check whether the receiving equipment or grid operator allows temporary off-specification gas | Choose a treatment train against the actual delivery specification rather than a generic “high-purity” target |
| Sampling and data quality | Analyzer calibration, sample location, sampling frequency, and wet/dry reporting basis | Use measurements representative of the gas entering the purification system | Compare continuous readings with periodic laboratory or validated field measurements | Reliable design data reduces the risk of undersizing pretreatment or selecting a process that cannot handle real operating conditions |